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August
15, 2002
Scripps Contacts:
Mario Aguilera or Cindy Clark, 858/534-3624; E-mail: scrippsnews@ucsd.edu
University of New Mexico Contact: Steve Carr, 505/277-1821
University of New Mexico
and Scripps Institution of Oceanography Researchers Find Central American
Volcanoes Yield New Clues about Earth Processes
Surprise' finding
shows nitrogen is quickly recycled through subduction zones
Images available upon request. See "Volcano Expedition" website
at: http://www.sio.ucsd.edu/volcano/
A
chain of Central America's most active volcanoes has given a team of researchers
from the University of New Mexico (UNM), Scripps Institution of Oceanography,
and Northern Illinois University a novel glimpse into fundamental Earth
processes. Their research, published in the Aug. 16 issue of the journal
Science, gives new insight into the past and possibly the future of elements
cycling between Earth's underlying mantle and surface reservoirs such
as the crust, oceans, and atmosphere.
The collaborative study was initially
conducted on Costa Rican volcanoes in January 2001 (descriptions of the
expedition are available online at scripps.ucsd.edu/volcano). A second
expedition concentrated on Guatemalan volcanoes in May 2001.
These volcanoes and others throughout
Central America are created by subduction, a process by which the offshore
Cocos plate slips beneath the Caribbean plate and is driven down into
Earth's mantle. The researchers sampled gases, or volatiles, discharged
from the volcanoes, and analyzed the nitrogen and helium compositions
to trace their sources.
The heart of the study concerned comparing gases from the two volcanic
regions. Through samples of sediment taken offshore, the researchers knew
the materials being driven into the subduction zone were virtually the
same between the two areas. The volatiles that came out, specifically
nitrogen gas, were "a big surprise," however.
In
the Guatemalan volcano system, nitrogen was driven down deep into the
subduction zone before rising back to Earth's surface. Costa Rica was
a different story. Here the scientists found no evidence that nitrogen
was cycling from the subducting plate. In this respect, the nitrogen characteristics
were consistent with other lines of geochemical evidence showing that
the top section of the sedimentary veneer on the Cocos plate had been
removed by the subduction process (for example, by plating to the overriding
Caribbean plate) before it reached the zone of arc magma generation.

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"The research is significant
because, first of all, not much is known about nitrogen coming out of volcanoes,"
said Tobias Fischer, a volcanologist at UNM's Department of Earth and Planetary
Sciences specializing in volcanic gas chemistry. "People thought it
was just air mixed in with volcanic gases. We clearly show that in the Guatemalan
subduction zone up to 95 percent of the nitrogen in volcanic gases comes
from subducted marine sediments. The situation is different in Costa Rica,
where the nitrogen is predominantly of mantle origin," said Fischer.
"We also show," adds
David Hilton, a geochemist from Scripps, "that the sedimentary nitrogen
is recycled back to the atmosphere through arc volcanism in Central America
and does not get subducted into the deeper mantle. We have clearly identified
the transport medium for nitrogen and show that it comes straight back
out to the Earth's surface through active volcanoes."
The study, one of the first clear descriptions of how and where nitrogen
travels during subduction, gives researchers a new glimpse into the long-term
evolution of Earth's mantle.
"This
is the kind of basic research that is important to investigate the nitrogen
cycle in the earth and the evolution of nitrogen in the mantle and in
the atmosphere," said Fischer. "We hope that our work will contribute
to the general understanding of the earth's global geochemical cycles
that have been operating for millions of years and continue
to influence the composition of the atmosphere."
"Volcanoes are basically transfer conduits between the earth's surface
and the underlying mantle," explains Hilton. "Consequently,
they are very important to geochemists who want to understand the evolution
of the earth. They're unique in allowing access to a remote region of
the earth."
The researchers now plan to address nitrogen and helium relationships
in other subduction zones mainly found bordering the Pacific Ocean (the
so-called "Ring of Fire") as well as at mid-ocean ridges and
oceanic hotspots such as Hawaii in an effort to elicit additional clues
about how gases move and cycle between Earth's mantle and atmosphere.
In
addition to Fischer and Hilton, coauthors of the study include Mindy Zimmer
and Zachary Sharp of the University of New Mexico, Alison Shaw of Scripps,
and James Walker of Northern Illinois University.
The research was supported by the National Science Foundation.
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